CHEM 2060

Exam #3

Study Guide

Know IUPAC nomenclature (like 10.2 and 10.26-10.28 pgs. 295; 321-322).

Know that amines have unusually high boiling points due to hydrogen bonding (like

Be able to predict order of basicity for a list of compounds (including heterocyclic

amines) (like 10.34 pg. 322).

Know different types of reductions to prepare amines (pgs. 309-311 and like

10.37-10.41 pg. 323).

Know preparations of amides with acid chlorides and sulfonyl chlorides

(like connections 10.4 pg. 310).

Know reagents needed to form a diazonium salt and be able to do subsequent

replacement reactions (Fig. 10.3 pg. 313 and like 10.44 pg. 323) or

coupling reactions to form azo compounds (like general reaction top of pg. 314).

Know IUPAC nomenclature (like 11.25, 11.26 and 11.29 pgs. 354-355).

Know preparations of aldehydes and ketones (pgs. 329-331 and like 11.31 pg. 355).

Know that aldehydes can be oxidized to carboxylic acids with Tollen's reagent,

Know addition reactions to aldehydes and ketones (Table 11.1 pg. 334 and like 11.33,

11.35 and 11.36 pgs. 355-356).

Know examples of bold terms such as Grignard reagent, hemiacetals, acetals, tautomers

(like 11.35, 11.41 and 11.44 pgs. 356-357).

Know IUPAC nomenclature for carboxylic acids and salts (pgs. 373-375 and 382-383)

especially know Table 12.1 pg. 361 (like 12.18, 12.21, and 12.23 pgs. 372-373).

Know common names for carboxylic acids up through caproic acid (Table 12.2 pg. 363).

Know that carboxylic acids have unusually high boiling points due to hydrogen

bonding and that acids are higher boiling than other functional groups of similar

Know the general structure of a carboxylic acid dimer (pg. 363).

Know acid reactions on pgs. 364-365.

Know structure/acidity relationship (pgs. 367-368; like 12.29 pg. 374).

Know preparations (pgs. 370-371).